The former Pussycat Doll showed off her toned figure in a red crop top with floral detail, which she paired with a black leather pencil skirt with a colourful starry pattern and black, lace-up ankle boots.
Nicole Scherzinger looked stunning at the Matthew Williamson SS15 show
Nicole kept her make up natural, while her hair was styled into stunning tousled waves swept to one side, a beauty look she kept when she later headed to the Temperley London show.
The stunning singer was joined on the front row by fashionistas Olivia Palermo and Poppy Delevingne who stepped out to watch the designer unveil his new collection.
Olivia was spotted earlier the day in a pale grey and white ensemble for the Whistles SS15 presetnation, however she changed into a purple, multi-patterned dress with a popped up collar for Matthew's show.
The stunning socialite paired her outfit with quirky sunglasses and some black flats with floral embellishment, adding a classic grey clutch bag to finish off her outfit.
Meanwhile, British beauty Poppy was the epitome of laidback glamour in a slogan jumper teamed with a black and white feathered skirt and black strappy heels. The 27-year-old added a pop of colour to her ensemble, opting for a red clutch bag.
It's not the first front row which Poppy and Olivia have shared this season, as the pair were seen kicking off New York Fashion Week together at the Desigual Spring 2015 catwalk show.
Olivia Palermo, Poppy Delevingne and Cat Deeley also graced the front row at the SS15 show
Another familiar face at Matthew's presentation was TV presenter Cat Deeley, who was spotted at Whistles with Olivia earlier in the day.
Cat started off the day in a plain white sleeveless shift dress with a pleated hem and snakeskin two-strap sandals, but changed into a different look for Matthew's show.
The So You Think You Can Dance host looked stunning in a blazer and black top, showing off her toned legs in skinny embellished trousers paired with black boots.
Adding a bit of glamour with some sparkling jewellery, Cat kept the rest of her accessories simple, opting for a red leather bag.