Cheryl Cole's BFF was stunning in a white gown complete with a thigh high split and keyhole cutout. She upped the glamour factor even further with red lips, long, spidery eyelashes and drop earrings.
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Also sporting pale hues on the red carpet was Kimberly's bandmate Sarah Harding, former Pussycat Doll star Ashley Roberts and popstar Pixie Lott.
Sarah stunned in a floor-sweeping gold sequin gown that featured a leopard print sheer neckline panel. The blonde star paired the dress with a clashing gold clutch bag.
Ashley was rocking a similar look in a gold sequin gown with gold chain straps. The singer posed over her shoulder to show off the backless creation.
Meanwhile, a host of stars chose classic black for the red carpet. Ashley's former bandmate Nicole Scherzinger was every inch the Hollywood beauty in a strapless black velvet gown that hugged her curves. Side-swept curls and silver drop diamond earrings completed the high-octane look.
Amanda Holden opted for a more demure version, sporting a high-neck slinky black maxigown.
Christine Bleakley tapped into the monochrome trend, wearing a black and white halter-neck gown with satin panels. The tight-fitting number perfectly flattered Christine's slender physique.
Also wowing on the red carpet was girlband The Saturdays. The girls were suitably glammed up for the occasion, all showing off different looks.
New mum Rochelle Humes wowed in a sheer panelled, nude sequin dress and purple lips, while HELLO! Online blogger Una Healy rocked a white graphic patterned dress and heavy eyeliner.
Vanessa White went for a more seductive look in a spaghetti strap velvet black gown by Wondaland, while Mollie King opted for black and nude horizontal stripes. Red lips topped off her look.