The mum-of-four struck her signature pose in the sheer-sleeved blouse with wool and satin panels with a black asymmetrical flounced mini skirt.
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She accessorised with a wide belt, peeptoe shoe boots and aviator sunglasses. Her hair had been swept back into a slightly dishevelled ponytail.
Joining Victoria at the fashion 'do were fellow A-listers Lea Michele and Diane Kruger and 50 Shades of Grey star Dakota Johnson.
Glee star Lea wore a gorgeous cream strapless Calvin Klein jumpsuit that showed off her svelte physique. Completing the look was a powder blue necklace, pointy black shoes and dramatic eye make-up.
Lea Michelle, Lily Collins and Dakota Johnson
Lea struck a pose with actress Lily Collins, who looked typically stylish in her patchwork shirt and white skirt.
Dakota, meanwhile, wore a figure-hugging, sweetheart neckline baby blue dress that featured black shoulder panelling.
It was recently announced that joining Dakota in the upcoming 50 Shades film will be former Calvin Klein underwear model Jamie Dornan.
The handsome 31-year-old dated Keira Knightley, has modelled alongside Kate Moss and starred in a film with Kirsten Dunst.