Doutzen wowed fans as she stepped out in a black dress with silver detail, as well as sheer panelling that showed off her toned stomach just three months after giving birth to her second child.
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Doutzen Kroes wowed in a black dress with sheer panelling
The 29-year-old rocked edgy slicked back hair for the event, and opted for barely-there make-up except for a slick of black eyeliner.
The Dutch model accessorised with a dazzling pair of earrings, and finished off her ensemble with a pair of black patent stilettos.
Joining Doutzen on the red carpet was fellow Victoria's Secret angel Karlie Kloss, who was all smiles as she posed for the event.
The 22-year-old was sporting a more grown-up look than she usually favours, wearing a floor length satin dress featuring green and white floral detail on the top, and a chic black skirt.
Karlie Kloss took a break from training for the Victoria's Secret Fashion Show
Like Doutzen, Karlie kept her accessories to a minimum, opting for a clutch bag matching her dress, completing her ensemble with a pair of black stilettos.
When it came to beauty, the American model chose for a dark ruby red shade of lipstick, keeping the rest of her make-up simple for a particularly striking effect. She finished off the look by tying her hair into a chic top knot, for ultimate red carpet glamour.
The ceremony saw some of the industry's biggest names stepping out in glitzy outfits, from iconic singer Madonna to actress Jennifer Connelly and model Joan Smalls.