The Duchesses also spoke with Nicole Christie, a graduate of Charles' The Modern Artisan programme.
She has now set up her own luxury womenswear line - Ellipsis - making exquisite dresses as well as hair accessories and bags from 100 per cent silk off-cuts, sourced in the UK, that would normally be discarded as part of the mass production process.
The royal visitors were delighted when Nicole, 26, from East Kilbride, Scotland, gave them a stunning cream silk pouch bag each - and a pretty pink scrunchie for Princess Charlotte - while Kate admired a stunning beige silk dress.
The Modern Artisan initiative, which saw The Prince's Foundation team up with Net-a-Porter, to create a luxury sustainable fashion range, had a "huge influence" on her life, Nicole said, and inspired her to set up Ellipsis 18 months ago.
She said: "The Modern Artisan shaped my business, Ellipsis, to what it is today. I didn't know about sustainability, they taught me the importance of keeping traditional skills alive.
"I showed the Duchesses my collection and I gave them one of my bags each that are due to launch in March. Everything is designed, patterned and hand-made by myself. I don't know what Ellipsis would have been if it hadn't been for the Prince."
She added: "The Prince came over and knew who I was. It's been a real honour to be part of this journey."