The stylish royal, dressed in a Victoria Beckham design, stole the show as she appeared from Bagshot Park to talk all things fashion.
But there was an extra treat in store for royal fans, who were given another glimpse inside Sophie's beautiful home.
WATCH: Sophie Wessex shares a look inside her kitchen at Bagshot Park
Eagle-eyed fans were quick to spot a striking family photo in the background, set on a side table behind the Countess.
The black-and-white image shows Sophie with her husband of 21 years, Prince Edward, with the Countess seen tenderly resting her head on his shoulder as they smile for the camera.
The black-and-white snapshot was visible behind Sophie
Another image taken from the event shows Sophie stood in one of Bagshot Park's beautiful rooms, with further family photos on display.
Sophie is stood in front of a wooden display cabinet featuring an array of ornamental plates – but taking pride of place is a snapshot that appears to be of Prince Edward and Lady Louise taken at the Duke and Duchess of Cambridge's wedding in 2011, at which the then-seven-year-old acted as a bridesmaid.
A wedding picture was also visible in another image from the virtual event
During her chat with the British Fashion Council, Sophie was asked about her personal style icons.
Asked whose style she most admired, the 56-year-old replied: "Angelina Jolie - I always think she looks amazing - and also Queen Rania of Jordan always looks stunning."
Prince Edward and Sophie have called Bagshot Park in Surrey their home for more than 20 years now. It is located approximately 11 miles south of Windsor, where the Queen and Duke of Edinburgh are staying at Windsor Castle.
Prince Edward and Sophie with Lady Louise and James, Viscount Severn
Spanning 51 acres, the property sits within a designated area of Windsor Great Park, which is adjacent to the private Home Park where Windsor Castle is situated.
In a past interview with Sky News, the Countess explained: "We're a lot more fortunate because we live so close to the Queen, so when she spends a lot of time at Windsor on the weekends, our children are more fortunate because they can go over and have tea with her on a regular basis."
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