However, the former pair have come a long way from the days fans thought they were endgame, and since their shocking 2016 split, the two have had an acrimonious dissolution of their nearly two-year marriage, marred with legal disputes and even accusations of assault.
In their time together, the once beloved couple shared kids Maddox, 21, Pax, 19, Zahara, 18, Shiloh, 17, and twins Vivienne and Knox, 15, and while they have all made public appearances with their mom since, it's unclear if they've become estranged from their father.
Zahara for one, recently made waves when the world got to see a glimpse of her life as a college student, at famed HBCU Spelman College in Atlanta, Georgia.
The sophomore was seen in a video shared on Essence's Instagram page, ecstatic as she was officially welcomed into the Alpha Kappa Alpha (AKA) Sorority, the first intercollegiate historically African American sorority, and one stars and dignitaries such as Jada Pinkett-Smith, GMA's Robin Roberts, US Vice President Kamala Harris and Rosa Parks were all members of as well.
In the video, Zahara was seen introducing herself to her sorority sisters as Zahara Marley Jolie, noticeably dropping the Pitt that was once hyphenated to her mom's last name name growing up.
When Zahara was first admitted to the school last year, her mom Angelina took to Instagram to celebrate the news, sharing an adorable photo of her daughter smiling next to fellow students, and she wrote in the caption: "Spelman sisters."
The very day the Maleficent actress announced her daughter's incredible milestone, Brad was on the red carpet while promoting his film Bullet Train, and was captured getting choked up when he was asked by People about Zahara's next step.
"Yeah, that's beautiful, it's really beautiful," he told the outlet at the time, seemingly taken aback, though later also telling Vanity Fair: "I'm so proud of her… She's so smart. She's going to flourish even more at college. It's an exciting and beautiful time to find her own way and pursue her interests. I'm so proud."
At the time, some fans wondered in the comments section under the video whether the actor was still in communication with his daughter, with some even questioning whether he was aware of her recent college decision.
Still, he further told VF: "Where does the time go, right? They grow up too fast… It brings a tear to the eye."
Though since her split from Brad, Angelina has been spotted out on multiple occasions with her six kids, it has been several years since her ex-husband was seen in public with any of them.
In 2021, a judge gave them 50-50 custody of the children after a closed-door trial, however Angelina has slammed the decision for bias, and had previously fought for sole custody.
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